Publisher DOI: 10.1016/j.heliyon.2024.e24770
Title: Degradation of a poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) compound in different environments
Language: English
Authors: Lyshtva, Pavlo 
Voronova, Viktoria 
Barbir, Jelena 
Leal Filho, Walter  
Kröger, Silja Denise 
Witt, Gesine  
Miksch, Lukas 
Sabowski, Reinhard 
Gutow, Lars 
Frank, Carina 
Emmerstorfer-Augustin, Anita 
Agustin-Salazar, Sarai 
Cerruti, Pierfrancesco 
Santagata, Gabriella 
Stagnaro, Paola 
D'Arrigo, Cristina 
Vignolo, Maurizio 
Krång, Anna-Sara 
Strömberg, Emma 
Lehtinen, Liisa 
Annunen, Ville 
Keywords: PHBV; Polymer blends; Degradation; Natural environment; Laboratory scale testing; Morphological properties
Issue Date: 15-Feb-2024
Publisher: Elsevier
Journal or Series Name: Heliyon 
Volume: 10
Issue: 3
Project: Sustainable solutions for bio-based plastics on land and sea 
Abstract: 
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is a promising biodegradable bio-based material, which is designed for a vast range of applications, depending on its composite. This study aims to assess the degradability of a PHBV-based compound under different conditions. The research group followed different methodological approaches and assessed visual and mass changes, mechanical and morphological properties, spectroscopic and structural characterisation, along with thermal behaviour. The Ph-Stat (enzymatic degradation) test and total dry solids (TDS)/total volatile solids (TVS) measurements were carried out. Finally, the team experimentally evaluated the amount of methane and carbon dioxide produced, i.e., the degree of biodegradation under aerobic conditions. According to the results, different types of tests have shown differing effects of environmental conditions on material degradation. In conclusion, this paper provides a summary of the investigations regarding the degradation behaviour of the PHBV-based compound under varying environmental factors.

The main strengths of the study lie in its multi-faceted approach, combining assessments of PHBV-based compound degradability under different conditions using various analytical tools, such as visual and mass changes, mechanical and morphological properties, spectroscopic and structural characterization, and thermal behavior. These methods collectively contribute to the robustness and reliability of the undertaken work.
URI: http://hdl.handle.net/20.500.12738/15379
ISSN: 2405-8440
Review status: This version was peer reviewed (peer review)
Institute: Fakultät Life Sciences 
Department Gesundheitswissenschaften 
Department Umwelttechnik 
Forschungs- und Transferzentrum Applied Life Science Technologies and Environmental Research 
Type: Article
Additional note: article number: e24770
Funded by: Europäische Kommission 
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